Vol. 17, issue 01, article # 4

pdf Buldakov M. A., Cherepanov V. N. Semiempirical dipole moment functions of the CO and NO molecules . // Atmospheric and oceanic optics. 2004. V. 17. No. 01. P. 34-38.
Copy the reference to clipboard
Abstract:

A semiempirical method has been developed for calculation of the dipole moment functions for the NO and CO molecules in the piecewise-continuous form. The dipole moment functions obtained exhibit a physically correct asymptotic behavior at small and large internuclear separations and agree with the dipole moment functions near the nuclear equilibrium position of the molecule. Within the framework of this approach, the account for the multipole and exchange interactions allows us to improve the dipole moment functions at large internuclear separations, including the range of slight overlapping of electron shells of the interacting atoms.