Vol. 3, issue 06, article # 3

pdf Voitsekhovskaya O. K. Calculation of the vibrational-rotational structure of the spectrum of water for the temperature range 300-2500ºK. // Atmospheric and oceanic optics. 1990. V. 3. No. 06. P. 533-539.
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Abstract:

The original set (up to second order inclusively) of derivatives of the dipole moment of H2O was determined by solving the inverse electrooptical problem based on the integral intensities, measured experimentally at the normal temperatures, of the vibrational transitions whose wave function incorporates vibrational resonances and anharmonicity. The obtained set was used to extrapolate (to T~2500ºK) the integral intensities of the band formed by transitions with high quantum numbers (V≤4). The centers and intensities of the vibrational-rotational lines of H2O were calculated and a data base was constructed for the parameters of the spectral lines of H2O for the temperature range 300-2500ºK.

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