Vol. 4, issue 06, article # 3

pdf Starikov V. I., Mikhailenko S. N. New resonances in an H2O molecule. // Atmospheric and oceanic optics. 1991. V. 4. No. 06. P. 424-429.
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Abstract:

The dependence of resonance parameters of an H2O molecule on the vibrational quantum number V2 , associated with the deformation vibration of high amplitude, is numerically studied. A significant change in the inverse inertia tensor μzz due to this vibration and its anharmonicity gives rise to the new types of resonances for which the ordinary conditions of proximity of the frequencies ω1≈ω3≈ 2ω2 are violated.