Vol. 4, issue 07, article # 9

pdf Bokov O. G., Sidorov N. K. Electrooptical parameters of molecules polarizabilities of chemical bonds. // Atmospheric and oceanic optics. 1991. V. 4. No. 07. P. 524-532.
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Abstract:

A review of the methods for solving the inverse electrooptical problem of molecular optics is presented. The reasons for the uncertainty in semiempirical determination of the principal values of the molecular polarizability tensor are analyzed and the necessity of solving the inverse problem based on the use of the valence–optical (VO) theory is shown. Based on the invariant expression for the molecular polarizability anisotropy ( O.G. Bokov, Atm. Opt. 3 No. 9, 827-839 (1990)) invariant equations have been derived for calculating the electrooptical parameters (EOP's), i.e., of the chemical bond polarizabilities of diatomic and hexatomic molecules. The EOP's of the twenty five molecules presented in the atmosphere as their main components or pollutants have been calculated.