OPTIKA ATMOSFERY I OKEANA JOURNAL
V.E. ZUEV INSTITUTE OF ATMOSPHERIC OPTICS
Vol. 4, issue 11, article # 10
pdf Gal'tsev A. P., Kuznetsov M. N. On the role of detailed balance in the line mixing treatment. // Atmospheric and oceanic optics. 1991. V. 4. No. 11. P. 821-824.Copy the reference to clipboard
Abstract:
A theoretical study of spectral line mixing is carried out on the basis of the general expression for detailed balance, providing thermodynamic equilibrium in a gas phase. Results of calculations are compared with those obtained using the model of strong collisions and the model of weak line coupling. It is shown that the absorption in the wings of rovibrational bands calculated for these cases may differ from measured values by an order of magnitude.