Vol. 33, issue 08, article # 1

Starikov V. I. Universal analytical function for calculations of broadening of H2S absorption lines by noble gases. // Optika Atmosfery i Okeana. 2020. V. 33. No. 08. P. 583–590. DOI: 10.15372/AOO20200801 [in Russian].
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Abstract:

A universal function is suggested for calculation of the A-broadening coefficients g of H2S absorption lines (A = He, Ne, Ar, Kr, and Xe). Only one parameter of this function depends on the broadening gas atom, while other parameters are common for all atoms. This parameter determines the ratio ν(А)/ν(А´) for A and A´ atoms. Parameters of the function are determined in the fitting procedure from the coefficients γ measured and calculated for ν1, ν2, and ν3 vibrational bands of H2S molecules. The coefficients g calculated are statistically compared with measurements. With the exception of some data for the ν1 and ν3 bands, the calculated and measured γ are in a good agreement for all collisional partners A.

Keywords:

hudrogen sulphide, noble gas broadening, analytical model

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