At the end of winter and beginning of spring of 2011 significant negative anomalies of nitrogen dioxide were detected on the basis of results obtained from the ground-based spectrometric measurements of the stratospheric NO2 content in Tomsk (West Siberia) and Zhigansk (East Siberia). Negative anomalies of NO2 were observed in other years too, but in 2011 they were record. Negative anomalies of NO2 were accompanied by anomalies of total ozone content (TOC), temperatures, and heights of the isobaric surfaces in stratosphere. The analysis of the transport atmospheric trajectories and horizontal TOC distribution demonstrated that the stratospheric NO2 content decrease was caused by the transport of stratospheric air from low TOC area. Vertical NO2 profiles in Tomsk show that, most probably, some contribution to the negative anomalies in the early spring of 2011 brought by denitrification of the polar stratosphere in ozone hole area.
nitrogen dioxide, ozone, ozone hole, anomalies
1. Solomon S. The mystery of the Antarctic ozone “Hole” // Rev. Geophys. 1988. V. 26, N 1. P. 131–148.
2. Manney G.L., Santee M.L., Rex M., Livesey N.J., Pitts M.C., Veefkind P., Nash E.R., Wohltmann I., Lehmann R., Froidevaux L., Poole L.R., Schoeberl M.R., Haffner D.P., Davies J., Dorokhov V., Gernandt H., Johnson B., Kivi R., Kyro E., Larsen N., Levelt P.F., Makshtas A., McElroy C.T., Nakajima H., Parrondo M.C., Tarasick D.W., von der Gathen P., Walker K.A., Zinoviev N.S. Unprecedented Arctic ozone loss in 2011 // Nature (Gr. Brit.). 2011. V. 478, N 7370. P. 469–475.
3. Balis D., Isaksen I.S.A., Zerefos C., Zyrichidou I., Eleftheratos 1 K., Tourpali K., Bojkov R., Rognerud B., Stordal F., Sovde O.A., Orsolini Y. Observed and modelled record ozone decline over the Arctic during winter/spring 2011 // Geophys. Res. Lett. 2011. V. 38. L23801. DOI: 10.1029/2011GL049259.
4. Sinnhuber B.-M., Stiller G., Ruhnke R., von Clarmann T., Kellmann S., Aschmann J. Arctic winter 2010/2011 at the brink of an ozone hole // Geophys. Res. Lett. 2011. V. 38. L24814. DOI: 10.1029/2011GL049784.
5. Feng W., Chipperfield M.P., Davies S., Mann G.W., Carslaw K.S., Dhomse S., Harvey L., Randall C., Santee M.L. Modelling the effect of denitrification on polar ozone depletion for Arctic winter 2004/2005 // Atmos. Chem. Phys. 2011. V. 11, N 13. P. 6559–6573.
6. Gruzdev A.N., Elohov A.N. Otricatel'naja anomalija stratosfernogo soderzhanija NO2 nad Zvenigorodom v konce marta – nachale aprelja 2011 year. // Dokl. RAN. 2012. V. 447, N3. P. 326–330.
7. Elohov A.S., Gruzdev A.N. Izmerenija obshhego soderzhanija i vertikal'nogo raspredelenija NO2 na Zvenigorodskoj nauchnoj stancii // Izv. RAN. Fiz. atmosf. i okeana. 2000. V. 36, N6. P. 831–846.
8. Gruzdev A.N., Elohov A.N. Validacija rezul'tatov izmerenij soderzhanija NO2 v vertikal'nom stolbe atmosfery s pomoshh'ju pribora OMI s borta sputnika EOS-Aura po dannym nazemnyh izmerenij na Zvenigorodskoj nauchnoj stancii // Izv. RAN. Fiz. atmosf. i okeana. 2009. V. 45, N4. P. 477–488.
9. Gruzdev A.N. Shirotnaja zavisimost' variacij stratosfernogo soderzhanija NO2 // Izv. RAN. Fiz. atmosf. i okeana. 2008. V. 44, N3. P. 345–359.
10. Gruzdev A.N. Latitudinal structure of variations and trends in stratospheric NO2 // Int. J. Remote Sens. 2009. V. 30, N 15/16. P. 4227–4246.
11. Gruzdev A.N. O nedel'noj ciklichnosti v atmosfere // Dokl. RAN. 2011. V. 439, N3. P. 407–412.