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Vol. 28, issue 05, article # 5

Bykov A. D., Lavrentieva N. N., Sinitsa L. N. Effects of strong vibrational excitation in water vapor spectroscopy. // Optika Atmosfery i Okeana. 2015. V. 28. No. 05. P. 417-429. DOI: 10.15372/AOO20150505 [in Russian].
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Abstract:

High-sensitive spectrometers, created at IAO SB RAS for studying highly excited states, are described. The spectrometers include a Fourier spectrometer with a multipath absorption cell and spectrometers that use modern methods of highly sensitive laser spectroscopy (intracavity laser spectrometers, spectrometers with a high quality external cavity). Designed spectrometers have a high spectral resolution (0.01…0.001 cm–1) and high sensitivity to absorption (10–7 – 3 × 10–9 cm–1), which makes them promising for the study of parameters of spectral lines arising from transitions to high-energy vibrational-rotational states.
The effects of the vibrational-rotational dynamics related to the chaotic behavior under strong excitation are considered by analyzing spectra of water vapor. They are: an anomalous centrifugal distortion, HEL-resonances in H2O, the nn3 highly excited states of the HD16O, the vibrational dependence of the line contour parameters, and the effect of intramolecular resonances on interference lines.

Keywords:

spectrometers, vibrational-rotational states, resonances, asymmetric top, potential surface, line broadening, line contour, intermolecular interactions

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