Vol. 39, issue 07, article # 10

Bobrovnikov S. M., Gorlov E. V., Zharkov V. I., Murashko S. N. Double-pulse laser fragmentation/laser-induced fluorescence of surface traces of nitrocompounds. // Optika Atmosfery i Okeana. 2026. V. 39. No. 07. P. 619–623. DOI: 10.15372/AOO20260710 [in Russian].
Copy the reference to clipboard
Abstract:

Ensuring security against threats associated with the use of explosive devices requires the development of effective methods for remote detection of explosive traces on different surfaces. This work discusses the way of improving the efficiency of the laser fragmentation/laser-induced fluorescence (LF/LIF) method for remote detection of surface traces of nitrocompounds. Using trinitrotoluene (TNT) as an example, it experimentally shows that time separation of fragmenting and probing pulses can significantly increase the efficiency of LF/LIF compared to single-pulse and simultaneous two-pulse irradiation. The relative intensity of fluorescence of NO fragments of TNT traces is assessed versus the fluence of fragmenting Nd:YAG laser (266.038 nm) and probing KrF laser (247.866 nm) at an optimal interpulse delay of 200 ns. The results can be used to improve the sensitivity and/or range of detection of nitrocompound traces by the LF/LIF method.

Keywords:

nitrocompound, laser fragmentation, nitric oxide, NO fragment, laser-induced fluorescence

References:

1. The Landmines, ERW and IED Safety Handbook. URL: https://www.unmas.org/en/landmines-erw-and-ied-safetyhandbook (last access: 09.09.2025).
2. Counterterrorist Detection Techniques of Explosives. URL: https://www.sciencedirect.com/book/9780444522047/counterterrorist-detection-techniques-of-explosives?via=ihub=#book-info (last access: 09.09.2025).
3. Rodgers M.O., Asai K., Davis D.D. Photofragmentation-laser induced fluorescence: A new method for detecting atmospheric trace gases // Appl. Opt. 1980. V. 19, N 21. P. 3597–3605. DOI: 10.1364/AO.19.003597.
4. Wu D.D., Singh J.P., Yueh F.Y., Monts D.L. 2,4,6-Trinitrotoluene detection by laser-photofragmentation–laser-induced fluorescence // Appl. Opt. 1996. V. 35, N 21. P. 3998–4003. DOI: 10.1364/AO.35.003998.
5. Simeonsson J.B., Sausa R.C. A critical review of laser photofragmentation/fragment detection techniques for gas phase chemical analysis // Appl. Spectrosc. Rev. 1996. V. 31, N 1. P. 1–72. DOI: 10.1080/05704929608000564.
6. Swayambunathan V., Singh G., Sausa R.C. Laser photofragmentation–fragment detection and pyrolysis–laser-induced fluorescence studies on energetic materials // Appl. Opt. 1999. V. 38, N 30. P. 6447–6454. DOI: 10.1364/ao.38.006447.
7. Daugey N., Shu J., Bar I., Rosenwaks S. Nitrobenzene detection by one-color laser photolysis/laser induced fluorescence of NO (v = 0–3) // Appl. Spectrosc. 1999. V. 53, N 1. P. 57–64. DOI: 10.1366/0003702991945227.
8. Shu J., Bar I., Rosenwaks S. Dinitrobenzene detection by use of one-color laser photolysis and laser-induced fluorescence of vibrationally excited NO // Appl. Opt. 1999. V. 38, N 21. P. 4705–4710. DOI: 10.1364/ao.38.004705.
9. Shu J., Bar I., Rosenwaks S. NO and PO photofragments as trace analyte indicators of nitrocompounds and organophosphonates // Appl. Phys. B. 2000. V. 71, N 5. P. 665–672. DOI: 10.1007/s003400000382.
10. Shu J., Bar I., Rosenwaks S. The use of rovibrationally excited NO photofragments as trace nitrocompounds indicators // Appl. Phys. B. 2000. V. 70, N 4. P. 621–625. DOI: 10.1007/s003400050870.
11. Arusi-Parpar T., Heflinger D., Lavi R. Photodissociation followed by laser-induced fluorescence at atmospheric pressure and 24°C: A unique scheme for remote detection of explosives // J. Appl. Opt. 2001. V. 40, N 36. P. 6677–6681. DOI: 10.1364/ao.40.006677.
12. Heflinger D., Arusi-Parpar T., Ron Y., Lavi R. Application of a unique scheme for remote detection of explosives // Opt. Commun. 2002. V. 204, N 1–6. P. 327–331. DOI: 10.1016/S0030-4018(02)01250-6.
13. Wynn C.M., Palmacci S., Kunz R.R., Zayhowski J.J., Edwards B., Rothschild M. Experimental demonstration of remote optical detection of trace explosives // Proc.SPIE. 2008. V. 6954. P. 695407–8. DOI: 10.1117/12.782371.
14. Wynn C.M., Palmacci S., Kunz R.R., Rothschild M. Noncontact detection of homemade explosive constituents via photodissociation followed by laser-induced fluorescence // Opt. Express. 2010. V. 18, N 6. P. 5399–5406. DOI: 10.1364/OE.18.005399.
15. Wynn C.M., Palmacci S., Kunz R.R., Aernecke M. Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence // Opt. Express. 2011. V. 19, N 19. P. 18671–18677. DOI: 10.1364/OE.19.018671.
16. Bobrovnikov S.M., Gorlov E.V., Zharkov V.I., Panchenko Y.N., Puchikin A.V. Dynamics of the laser fragmentation/laser-induced fluorescence process in nitrobenzene vapors // Appl. Opt. 2018. V. 57, N 31. P. 9381–9387. DOI: 10.1364/AO.57.009381.
17. Bobrovnikov S.M., Gorlov E.V., Zharkov V.I., Panchenko Y.N., Puchikin A.V. Two-pulse laser fragmentation/laser-induced fluorescence of nitrobenzene and nitrotoluene vapors // Appl. Opt. 2019. V. 58, N 27. P. 7497–7502. DOI: 10.1364/AO.58.007497.
18. Panchenko Y.; Puchikin A., Yampolskaya S., Bobrovnikov S.; Gorlov E.; Zharkov V. Narrowband KrF laser for lidar systems // IEEE J. Quant. Electron. 2021. V. 57, N 2. P. 1–5. DOI: 10.1109/JQE.2021.3049579.
19. Luque J., Crosley D.R. LIFBASE: Database and Spectral Simulation Program (Version 1.5). URL: https://www.sri.com/engage/products-solutions/lifbase (last access: 09.09.2025).