Vol. 34, issue 11, article # 7

Аntokhin P. N., Arshinova V. G., Arshinov M. Yu., Belan B. D., Belan S. B., Golobokova L. P., Davydov D. K., Ivlev G. A., Kozlov A. V., Kozlov A. S., Otmakhov V. I., Rasskazchikova T. M., Simonenkov D. V., Tolmachev G. N., Fofonov A. V. Differences in air composition between troposphere and stratosphere near tropopause. // Optika Atmosfery i Okeana. 2021. V. 34. No. 11. P. 874–881. DOI: 10.15372/AOO20211107 [in Russian].
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Abstract:

A change in the air composition during the transition from the troposphere to the stratosphere is investigated on the basis of aircraft sounding data. Distribution of eight gases, dispersion and chemical composition of aerosol is analyzed. It is shown that at the intersection of the tropopause, the concentrations of N2O, CO, and CH4 sharply decrease, while of O3 and NO2 and the counting concentration of aerosol, on the contrary, increase. In the elemental composition, Si dominates the tropopause; in the ion,  Terrigenous elements Al, Cu, and Fe are dominated in the troposphere; and among ions, a set of several compounds varies with region. Noticeably different particle dispersions are also identified.

Keywords:

atmosphere, aerosol, air, vertical distribution, gases, composition, stratosphere, troposphere

Figures:
References:

  1. Mahover Z.M. Klimatologiya tropopauzy. L.: Gidrometeoizdat, 1983. 254 p.
  2. Trickl T., Vogelmann H., Giehl H., Scheel H.-E., Sprenger M., Stohl A. How stratospheric are deep stratospheric intrusions? // Atmos. Chem. Phys. 2014. V. 14, N 18. P. 9941–9961.
  3. Trickl T., Bartsch-Ritter N., Eisele H., Furger M., Mucke R., Sprenger M., Stohl A. High-ozone layers in the middle and upper troposphere above Central Europe: Potential import from the stratosphere along the subtropical jet stream // Atmos. Chem. Phys. 2011. V. 11, N 17. P. 9343–9366.
  4. Kukoleva A.A. Otsenki potokov ozona cherez tropopauzu v planetarnyh vysotnyh frontal'nyh zonah severnogo polushariya // Izv. RAN. Fizika atmosf. i okeana. 2002. V. 38, N 3. P. 376–387.
  5. Ivanova A.R. Stratosferno-troposfernyj obmen i ego nekotorye osobennosti vo vnetropicheskih shirotah // Meteorol. i gidrol. 2016. N 3. P. 22–45.
  6. Krivolutskij A.A., Kukoleva A.A. Rezul'taty Rossijskih issledovanij srednej atmosfery (2011–2014 years) // Izv. RAN. Fizika atmosf. i okeana. 2016. Т. 52, № 5. С. 561–570.
  7. Boothe A.C., Homeyer C.R. Global large-scale stratosphere–troposphere exchange in modern reanalyses // Atmos. Chem. Phys. 2017. V. 17, N 9. P. 5537–5559.
  8. Runde T., Dameris M., Garny H., Kinnison D.E. Classification of stratospheric extreme events according to their downward propagation to the troposphere // Geophys. Res. Lett. 2016. V. 43, N 12. P. 6665–6672.
  9. Mihalikova M., Kirkwood S., Arnault J., Mikhaylova D. Observation of a tropopause fold by MARA VHF wind-profiler radar and ozonesonde at Wasa, Antarctica: Comparison with ECMWF analysis and a WRF model simulation // Ann. Geophys. 2012. V. 30, N 9. P. 1411–1421.
  10. Mihalikova M., Kirkwood S. Tropopause fold occurrence rates over the Antarctic station Troll (75 S, 2.5 E) // Ann. Geophys. 2013. V. 31, N 4. P. 591–598.
  11. Weigel K., Hoffmann L., Gunther G., Khosrawi F., Olschewski F., Preusse P., Spang R., Stroh F., Riese M. A stratospheric intrusion at the subtropical jet over the Mediterranean Sea: Air-borne remote sensing observations and model results // Atmos. Chem. Phys. 2012. V. 12, N 8. P. 8423–8438. 1
  12. Pisoft P., Sacha P., Polvani L.M., Añel J.A., de la Torre L., Eichinger R., Foelsche U., Huszar P., Jacobi C., Karlicky J., Kuchar A., Miksovsky J., Zak M., Rieder H.E. Stratospheric contraction caused by increasing greenhouse gases // Environ. Res. Lett. 2021. V. 16, N 6. P. 064038.
  13. Follette-Cook M.B., Hudson R.D., Nedoluha G.E. Classification of Northern Hemisphere stratospheric ozone and water vapor profiles by meteorological regime // Atmos. Chem. Phys. 2009. V. 9, N 16. P. 5989–6003.
  14. Collins W.J., Derwent R.G., Garnier B., Johnson C.E., Sanderson M.G., Stevenson D.S. Effect of stratosphere–troposphere exchange on the future tropospheric ozone trend // J. Geophys. Res. 2003. V. 108, N D12. P. 8528.
  15. Geng L., Murray L.T., Mickley L.J., Lin P., Fu Q., Schauer A.J., Alexander B. Isotopic evidence of multiple controls on atmospheric oxidants over climate transitions // Nature. 2017. V. 546, N 7656. P. 133–137.
  16. Crutzen P.J. Albedo enhancement by stratospheric sulfur injections: A contribution to resolve a policy dilemma? // Clim. Change. 2006. V. 77. P. 211–219.
  17. Ravishankara A.R. Water vapor in the lower stratosphere // Science. 2012. V. 337, N 6096. P. 809–810.
  18. Anderson J.G., Wilmouth D.M., Smith J.B., Sayres D.S. UV Dosage levels in summer: Increased risk of ozone loss from convectively injected water vapor // Science. 2012. V. 337, N 6096. P. 835–839.
  19. Ueyama R., Jensen E.J., Pfister L., Diskin G.S., Bui T.P., Dean-Day J.M. Dehydration in the tropical tropopause layer: A case study for model evaluation using aircraft observations // J. Geophys. Res.: Atmos. 2014. V. 119, N 9. P. 5299–5316.
  20. Schoeberl M.R., Selkirk H.B., Vömel H., Douglass A.R. Sources of seasonal variability in tropical upper troposphere and lower stratosphere water vapor and ozone: Inferences from the Ticosonde data set at Costa Rica // J. Geophys. Res.: Atmos. 2015. V. 120, N 18. P. 9684–9701.
  21. Rolf C., Afchine A., Bozem H., Buchholz B., Ebert V., Guggenmoser T., Hoor P., Konopka P., Kretschmer E., Müller S., Schlager H., Spelten N., Suminska-Ebersoldt O., Ungermann J., Zahn A., Krämer M. Transport of Antarctic stratospheric strongly dehydrated air into the troposphere observed during the HALO-ESMVal campaign 2012 // Atmos. Chem. Phys. 2015. V. 15, N 16. P. 9143–9158.
  22. Sofieva V.F., Tamminen J., Kyrölä E., Mielonen T., Veefkind P., Hassler B., Bodeker G.E. A novel tropopause-related climatology of ozone profiles // Atmos. Chem. Phys. 2014. V. 14, N 1. P. 283–299.
  23. Petropavlovskikh I., Ray E., Davis S.M., Rosenlof K., Manney G., Shetter R., Hall S.R., Ullmann K., Pfister L., Hair J., Fenn M., Avery M., Thompson A.M. Low ozone bubbles observed in the tropical tropopause layer during the TC4 campaign in 2007 // J. Geophys. Res. 2010. V. 115. P. D00J16. DOI: 10.1029/2009JD012804.
  24. Konopka P., Pan L.L. On the mixing-driven formation of the Extratropical Transition Layer (ExTL) // J. Geophys. Res. 2012. V. 117. P. D18301. DOI: 10.1029/2012JD017876.
  25. Berchet B., Paris J.-D., Ancellet G., Law K.S., Stohl A., Nedelec Ph., Arshinov M.Yu., Belan B., Ciais Ph. Tropospheric ozone over Siberia in spring 2010: Remote influences and stratospheric intrusion // Tellus B. 2013. V. 65. P. 19688.
  26. Homeyer C.R., Bowman K.P., Pan L.L., Atlas E.L., Gao R.-S., Campos T.L. Dynamical and chemical characteristics of tropospheric intrusions observed during START08 // J. Geophys. Res. 2011. V. 116. P. D06111. DOI: 10.1029/2010JD015098.
  27. Anohin G.G., Antohin P.N., Arshinov M.YU., Barsuk V.E., Belan B.D., Belan S.B., Davydov D.K., Ivlev G.A., Kozlov A.V., Kozlov V.S., Morozov M.V., Panchenko M.V., Penner I.E., Pestunov D.A., Sikov G.P., Simonenkov D.V., Sinitsyn D.S., Tolmachev G.N., Filippov D.V., Fofonov A.V., Chernov D.G., Shamanaev V.S., Shmargunov V.P. Samolet-laboratoriya Tu-134 «Optik» // Optika atmosf. i okeana. 2011. V. 24, N 9. P. 805–816.
  28. Otmahov V.I., Petrova E.V., Otmahova Z.I., Lapova T.V. Himiko-atomno-emissionnyj spektral'nyj analiz atmosfernyh i promyshlennyh aerozolej na soderzhanie tyazhelyh metallov // Optika atmosf. i okeana. 1999. V. 12, N 4. P. 341–344.
  29. Belan B.D., Ivlev G.A., Kozlov A.V., Rasskazchikova T.M., Simonenkov D.V., Tolmachev G.N. Typisation of the chemical composition of the tropospheric aerosol of the south of Western Siberia by the air mass // Proc. SPIE. 2018. V. 10833. DOI: 10.1117/12.2504604.
  30. Golobokova L.P., Khodzher T.V., Izosimova O.N., Zenkova P.N., Pochyufarov A.O., Khuriganowa O.I., Onishyuk N.A., Marinayte I.I., Polkin V.V., Radionov V.F., Sakerin S.M., Lisitzin A.P. and Shevchenko V.P. Himicheskij sostav atmosfernogo aerozolya v arkticheskom rajone po marshrutam morskih ekspeditsij 2018–2019 years // Optika atmosf. i okeana. 2020. V. 33, N 6. P. 421–429; Golobokova L.P., Khodzher T.V., Izosimova O.N., Zenkova P.N., Pochyufarov A.O., Khuriganowa O.I., Onishyuk N.A., Marinayte I.I., Polkin V.V., Radionov V.F., Sakerin S.M., Lisitzin A.P. and Shevchenko V.P. Chemical composition of atmospheric aerosol in the Arctic region and adjoining seas along the routes of marine expeditions in 2018–2019 // Atmos. Ocean. Opt. 2020. V. 33, N 5. P. 480–489. DOI: 10.15372/AOO20200601.
  31. Golobokova L.P., Khodzher T.V., Khuriganova O.I., Marinayte I.I., Onishchuk N.A., Rusanova P., Potemkin V.L. Variability of chemical properties of the atmospheric aerosol above lake Baikal during large wildfires in Siberia // Atmosphere. 2020. V. 11, N 11. P. 1230. DOI: 10.3390/atmos11111230.
  32. Ivanova A.R. Tropopauza-mnogoobrazie opredelenij i sovremennye podhody k identifikatsii // Meteorol. i gidrol. 2013. N 12. P. 23–36.
  33. Prather M.J., Zhu X., Tang Q., Hsu J., Neu J.L. An atmospheric chemist in search of the tropopause // J. Geophys. Res. 2011. V. 116. P. D04306. DOI: 10.1029/2010JD014939.
  34. Ivanova A.R. Naklon tropopauzy kak harakteristika ee deformatsii // Meteorol. i gidrol. 2011. N 2. P. 17–29.
  35. Hromov S.P. Osnovy sinopticheskoj meteorologii. L.: Gidrometeoizdat, 1948. 700 p.
  36. Matveev L.T. Kurs obshchej meteorologii. Fizika atmosfery. SPb.: Gidrometeoizdat, 2000. 777 p.
  37. Remsberg E.E. Methane as a diagnostic tracer of changes in the Brewer–Dobson circulation of the stratosphere // Atmos. Chem. Phys. 2015. V. 15, N 7. P. 3739–3754.
  38. Bozem H., Hoor P., Kunkel D., Köllner F., Schneider J., Herber A., Schulz H., Leaitch W.R., Aliabadi A.A., Willis M.D., Burkart J., Abbatt J.P.D. Characterization of transport regimes and the polar dome during Arctic spring and summer using in situ aircraft measurements // Atmos. Chem. Phys. 2019. V. 19, N 23. P. 15049–15071.
  39. Oelhaf H., Sinnhuber B.-M., Woiwode W., Bönisch H., Bozem H., Engel A., Fix A., Friedl-Vallon F., Grooß J.-U., Hoor P., Johansson S., Jurkat-Witschas T., Kaufmann S., Krämer M., Krause J., Kretschmer E., Lörks D., Marsing A., Orphal J., Pfeilsticker K., Pitts M., Poole L., Preusse P., Rapp M., Riese M., Rolf Ch., Ungermann J., Voigt Ch., Volk C.M., Wirth M., Zahn A., Ziereis H. POLSTRACC // Bull. Am. Meteorol. Sоc. 2019. V. 100, N 12. P. 2634–2664.
  40. Volz A., Enhalt D.H., Derwent R.G. Seasonal and latitudinal variations of 14CO and the tropospheric concentration of OH radicals // J. Geophys. Res. 1981. V. 86, N 5. P. 5163–5171.
  41. Enhalt D.H. The atmospheric cycle of methan // Tellus. 1974. V. 26, N 1. P. 58–70.
  42. Liang Q., Rodriguez J.M., Douglass A.R., Crawford J.H., Olson J.R., Apel E., Bian H., Blake D.R., Brune W., Chin M., Colarco P.R., da Silva A., Diskin G.S., Duncan B.N., Huey L.G., Knapp D.J., Montzka D.D., Nielsen J.E., Pawson S., Riemer D.D., Weinheimer A.J., Wisthaler A. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange // Atmos. Chem. Phys. 2011. V. 11, N 24. P. 13181–13199.
  43. Varotsos C., Christodoulakis J., Tzanis C., Cracknell A.P. Signature of tropospheric ozone and nitrogen dioxide from space: A case study for Athens, Greece // Atmos. Environ. 2014. V. 89. P. 721–730.
  44. Ivlev L.S. Himicheskij sostav i struktura atmosfernyh aerozolej. L.: Izd-vo LGU, 1982. 366 p.
  45. Shakina N.P., Kuznetsova I.N., Ivanova A.R. Analiz sluchaev stratosfernyh vtorzhenij, soprovozhdaemyh povysheniem radioaktivnosti v prizemnom vozduhe // Meteorol. i gidrol. 2000. N 2. P. 53–60.
  46. Cho H.-M., Hong Y.-L., Kim G. Atmospheric depositional fluxes of cosmogenic 35S and 7Be: Implications for the turnover rate of sulfur through the biosphere // Atmos. Environ. 2011. V. 45, N 25. P. 4230–4234.
  47. Jurkat T., Kaufmann S., Voigt Ch., Schäuble D., Jeßberger Ph., Ziereis H. The airborne mass spectrometer AIMS – Part 2: Measurements of trace gases with stratospheric or tropospheric origin in the UTLS // Atmos. Meas. Tech. 2016. V. 9, N 4. P. 1907–1923.
  48. Schneider J., Weigel R., Klimach T., Dragoneas A., Appel O., Hünig A., Molleker S., Köllner F., Clemen H.-Ch., Eppers O., Hoppe P., Hoor P., Mahnke Ch., Krämer M., Rolf Ch., Grooß J.-U., Zahn A., Obersteiner F., Ravegnani F., Ulanovsky A., Schlager H., Scheibe M., Diskin G.S., DiGangi J.P., Nowak J.B., Zöger M., Borrmann S. Aircraft-based observation of meteoric material in lower-stratospheric aerosol particles between 15 and 68N // Atmos. Chem. Phys. 2021. V. 21, N 2. P. 989–1013.