The transmission spectra of aerogel with nanopores filled with SO2 and a mixture of H2O and SO2 are studied The measurements were carried out using a Bruker IFS 125 HR Fourier spectrometer in the spectral range 4500–10000 cm-1 at a room temperature. It is found that the filling of nanopores of a sample with SO2 and with a binary mixture of H2O and SO2 molecules affects the absorption bands of the aerogel. This change is reversible: when gases are pumped out, the transmission spectrum of the aerogel sample is restored.
nanopore aerogel, SiO2, water vapor, IR spectrum
1. Ponomarev Yu.N., Petrova T.M., Solodov A.M., Solodov A.A. IR spectroscopy of water vapor confined in silica aerogel nanopores // Opt. Express. 2010. V. 18, N 25. P. 26062–26067.
2. Ponomarev Yu.N., Cherepanov V.N., Nasibulin R.T., Simonova A.A. Otsenka tipa orientatsii molekul H2O v adsorbirovannom sloe na poverkhnosti nanopor aerogelya SiO2 // Optika atmosf. i okeana. 2022. V. 35, N 8. P. 603–607; Ponomarev Yu.N., Cherepanov V.N., Nasibulin R.T., Simonova A.A. Estimation of H2O molecule orientation type in the adsorbed layer on a SiO2 aerogel nanopore surface // Atmos. Ocean. Opt. 2022. V. 35, N 6. P. 621–625.
3. Sinitsa L.N., Serdyukov V.I., Danilyuk A.F., Lugovskoi A.A. Observation of water dimers in nanopores of silicon aerogel // JETP Lett. 2015. V. 102, N 1. P. 32–35.
4. Petrova T.M., Ponomarev Yu.N., Solodov A.A., Solodov A.M., Danilyuk A.F. Spectroscopic nanoporometry of aerogel // JETP Lett. 2015. V. 101, N 1. P. 65–67.
5. Hartmann J.M., Boulet C., Vander Auwera J., Hamzaoui H.El., Capoen B., Bouazaoui M. Line broadening of confined CO gas: From molecule-wall to molecule-molecule collisions with pressure // J. Chem. Phys. 2014. V. 140, N 6. P. 064302.
6. Vander Auwera J., Ngo N.H., Hamzaoui H.E., Capoen B., Bouazaoui M., Ausset P., Boulet C., Hartmann J.M. Infrared absorption by molecular gases as a probe of nanoporous silica xerogel and molecule–surface collisions: Low-pressure results // Phys. Rev. A. 2013. V. 88. P. 042506.
7. Solodov A.A., Petrova T.M., Ponomarev Yu.N., Solodov A.M. Influence of nanoconfinement on the rotational dependence of line half-widths for 2–0 band of carbon oxide // Chem. Phys. Lett. 2015. V. 637. P. 18–21.
8. Petrova T.M., Ponomarev Yu.N., Solodov A.A., Solodov A.M., Glazkova E.A., Bakina O.V., Lerner M.I. IK-spektry pogloshcheniya CO2, C2H4, C2H v nanoporakh SiO2/Al2O3-aerogelya // Optika atmosf. i okeana. 2016. V. 29, N 5. P. 380–385; Petrova T.M., Ponomarev Yu.N., Solodov A.A., Solodov A.M., Glazkova E.A., Bakina O.V., Lerner M.I. Infrared absorption spectra of CO2, C2H4, C2H6 in nanopores of SiO2/Al2O3 aerogel // Atmos. Ocean. Opt. 2016. V. 29, N 5. P. 404–409.
9. Petrova T.M., Ponomarev Yu.N., Solodov A.A., Solodov A.M., Glazkova E.A. Upravlyaemoe spektral'noe prosvetlenie nanoporistogo SiO2/Al2O3-kserogelya pri ego zapolnenii ammiakom i atsetonom // Pis'ma v ZhETF. 2017. V. 105, N 9. P. 550–553.
10. Tarbuck T.L., Richmond G.L. Adsorption and reaction of CO2 and SO2 at a water surface // J. Am. Chem. Soc. 2006. V. 128. P. 3256–3267.
11. Tarbuck T.L., Richmond G.L. SO2 : H2O surface complex found at the vapor water interface // J. Am. Chem. Soc. 2005. V. 127. P. 16806–16807.
12. Poelz G. Aerogel Cherenkov counters at DESY // Nucl. Instr. Meth. A. 1986. V. 248. P. 118–119.
13. Bartholomew R.E., Butler B.L., Hoover H.L., Wu C.K. Infrared spectra of a water-containing glass // J. Am. Cer. Soc. 1980. V. 63. P. 481–485.
14. Marcu I.-C., Sandulescu I. Study of sulfur dioxide absorption on Y zeolite // J. Serb. Chem. Soc. 2004. V. 69, N 7. P. 563–569.
15. Deo A.V., Dalla Lana I.G. Infrared studies of the adsorption and surface reactions of hydrogen sulfide and sulfur dioxide on some aluminas and zeolites // J. Catal. 1971. V. 21. P. 270–281.
16. Waqif M., Saad A.M., Bensitel M., Bachelier J., Saur O., Lavalley J.-C. Comparative study of SO2 adsorption on metal oxides // J. Chem. Soc. Faraday Trans. 1992. V. 88. P. 2931–2936.
17. Informatsionnaya sistema «Spektroskopiya atmosfernykh gazov» SPECTRA [Elektronnyy resurs]. URL: https://spectra.iao.ru/.